Hydrogen Use / Utilización del Hidrógeno
Transcripción
Hydrogen Use / Utilización del Hidrógeno
InWent Workshop Buenos Aires 27+28 September 2007 Hydrogen Use / Utilización del Hidrógeno Reinhold Wurster Ludwig-Bölkow-Systemtechnik GmbH Ottobrunn / Germany [email protected] www.lbst.de Tabla de Contenido Situación de la disponibilidad de los recursos energéticos ludwig bölkow systemtechnik El papel del hidrógeno (H2) Sistema de producción, transporte y distribución de H2 Analisis de eficiencia energética y de emisiones de efecto climatico Potenciales de producción de H2 por fuentes renovables Costos de la producción y del uso vehícular del H2 Ejemplos de aplicación del H2 en el sector automotriz y estacionario 2 www.lbst.de Conversion efficiencies/ Eficiencias de conversión Ludwig-Bölkow-Systemtechnik GmbH, 2007 Nuclear heat to electricity Biomass to electricity 30% 33% 35% 40% Coal to electricity 50% Gas to electricity 16,000 98% Renewable electricity Combined heat and power 0% 40% Final Energy Supply "Conv ersion losses" 14,000 Heat 60% 25% 20% Total Primary Energy Supply 18,000 "Conv ersion losses" 12,000 60% 80% 100% Efficiency 10,000 [Mtoe] Oil to electricity ludwig bölkow systemtechnik Conversion losses Electricity 8,000 Ludwig-Bölkow-Systemtechnik GmbH, 2007 Coal to liquids 45% Coal to hydrogen 50% Gas to liquids 50% Biomass to liquids 50% 4,000 2,000 WEO 70% Biomass to hydrogen 70% Electricity and water to hydrogen 70% WEO LBST 2010 WEO LBST 2020 WEO LBST 2030 Total Primary Energy Supply and Final Energy Supply - w orld summary Ludw ig-Bölkow -Systemtechnik GmbH, 2007 90% Oil to fuel 20% 40% 60% Efficiency 3 LBST 2004 Gas to hydrogen 0% 6,000 Conversion losses Fuel 80% 100% www.lbst.de World energy supply by 2030/ Suministro energético mundial en 2030 ludwig bölkow systemtechnik 4 www.lbst.de Global future energy trends Pico en suministro de energías fosiles - petroleo ludwig bölkow systemtechnik Production in [Mtoe per year] 16,000 14,000 12,000 10,000 8,000 OIL PEAK 2005~2010 6,000 4,000 2,000 1930 5 Legend Oil Oil 1950 1970 1990 2010 2030 2050 2070 2090 Scenario assumption: decline rate after peak of 2.7%/yr Actual experience: decline rates of 10%/yr and beyond (e.g. Alaska, Mexico, Norway, Oman, UK) www.lbst.de Global future energy trends Pico en suministro de energías fosiles – gas natural ludwig bölkow systemtechnik Production in [Mtoe per year] 16,000 14,000 12,000 10,000 GAS PEAK 2015~2025 8,000 6,000 Gas 4,000 2,000 1930 6 Legend Gas Oil Oil 1950 1970 1990 2010 2030 2050 2070 2090 www.lbst.de Global future energy trends Pico en suministro de energías fosiles - carbon ludwig bölkow systemtechnik Production in [Mtoe per year] 16,000 14,000 12,000 10,000 COAL PEAK 2030~2040 Bituminous + subbituminous 8,000 Lignite coal 6,000 Gas 4,000 2,000 1920 7 Legend Coal lignite Coal bit+subbit Gas Oil Oil 1940 1960 1980 2000 2020 2040 2060 2080 For details on coal resource/reserve analysis, see EWG Report No. 1/ 2007 "Coal“: http://www.lbst.de/publications/studies__e/2007EWG-coal__e.html 2100 www.lbst.de Global future energy trends Pico en suministro de energías fosiles - uranio ludwig bölkow systemtechnik Production in [Mtoe per year] 16,000 14,000 12,000 10,000 NUCLEAR PEAK 2015~2020 Bituminous + subbituminous 8,000 Lignite coal Nuclear 6,000 Gas 4,000 2,000 1920 8 Legend Nuclear Coal lignite Coal bit+subbit Gas Oil Oil 1940 1960 1980 2000 2020 2040 2060 2080 For details on nuclear resource/reserve analysis, see EWG Report No. 1/2006 "Uranium“: http://www.lbst.de/publications/studies__e/2006EWG-uranium__e.html 2100 www.lbst.de Global future energy trends Pico en suministro de energías fosiles – sumación ludwig bölkow systemtechnik 16,000 Production in [Mtoe per year] WEO 2006 scenario 14,000 12,000 10,000 FOSSIL+NUCLEAR PEAK 2015~2020 Bituminous + subbituminous 8,000 Lignite coal Nuclear 6,000 Gas 4,000 2,000 1920 9 Legend Nuclear Coal lignite Coal bit+subbit Gas Oil Oil 1940 1960 1980 2000 2020 2040 2060 2080 2100 www.lbst.de Global future energy trends Perspectiva Global de Energía prparado por LBST Total primary energy supply in [Mtoe] 2004 2030 20,000 15,000 10,000 Legend Geothermal Hydro Wind Biomass Solar collectors SOT PV Uranium Coal Gas Oil Geothermal WEO 2006 Wind power Biomass Hydropower Solar collectors Uranium SOT Coal PV Gas 5,000 Oil 1930 10 ludwig bölkow systemtechnik 1950 1970 1990 2010 2030 2050 2070 2090 www.lbst.de Global future energy trends Tendencias generales – pico en combustible fosiles Rising domestic energy consumption and declining energy production ludwig bölkow systemtechnik Increasing energy prices (energy imports!) Shift to fuels with lower energy density: oilÆ natural gas Æ hydrogen Decrease of interregional energy trade – shifting to distributed, regional energy structures necessary Increase of use competition of carbon-based fuels (oil, gas, coal, biomass): pharmacy, food production, materials Demand of climate and environmentally friendly energy systems Increasing share of renewable energy production Increasing importance to produce fuels from electricity, and not only electricity from fuels 11 www.lbst.de Implicaciones para países en desarrollo Situación de importación/ exportación de energía en 2030 ludwig bölkow systemtechnik China, South Asia and East Asia will become net energy importers: China will become the world largest net energy importer; South Asia and East Asia will not be able to increase their net energy import balance by 2030 in view of increasing energy demand Æ either becoming more self-sufficient or threatened by energy crisis) Latin America will reduce its energy exports and will be focused on the intercontinental energy market (self-sufficient with fossil and renewable energies) Africa could become a major and important exporter of energy (mainly gas, coal, uranium, renewables) The Middle East and the Transition Economies will become the largest exporter of fossil fuels (mainly oil, gas, coal, uranium) [Remark: statements are dependent on the assumptions taken in defining the regional breakdown] 12 www.lbst.de Implicaciones para países en desarrollo Transición hacia el era post-carbonico ludwig bölkow systemtechnik Reduction of energy import dependency Sustainable energy structures are needed Development of regional and alternative energy structures: • build-up of renewable energies • investment in local infrastructures, e.g. electricity grids, water management • promotion of alternative fuels (domestic supply / export?) • support of local production of RES technology (local demand / export?) • promote energy saving technologies and energy efficiency 13 www.lbst.de Transición de combustibles fosiles a electricidad renovable ludwig bölkow systemtechnik 14 www.lbst.de Role of H2 and Fuel Cells/ Papel del hidrógeno y de pilas de combustible ludwig bölkow systemtechnik To incorporate a maximum of renewable energies… …we need the ability to produce fuel from electricity, not only electricity from fuel! 15 www.lbst.de Role of H2 and Fuel Cells/ Papel del hidrógeno y de pilas de combustible Hydrogen in stationary applications: ludwig bölkow systemtechnik  Efficiency of electricity→H2→electricity pathway is lower than with competing stationary technologies, thus only suited for island systems or on top of anything else Beside this, hydrogen…  is well suited as transportation fuel (potential, yield, storage, efficiency)  provides the broadest feedstock flexibility (from fossil to renewable)  offers a cross-cut from electricity to transportation fuels / energy storage. Hence, using hydrogen where it makes sense facilitates… → a 'greening' of the transport sector (sustainable fuel) → diversification of primary energy sources for transportation → increased security of supply for the transport sector → efficient load management for the stationary power sector through transportation fuel production 16 → take-up of more fluctuating renewables into the stationary electricity grid. www.lbst.de Role of hydrogen/ Papel del hidrógeno Que necesidades lo puede cubrir ? ludwig bölkow systemtechnik Combustibles Alternativos ? Transport sector: Local production of hydrogen (reduction of oil import dependency, long-term growth will not be Infraestructura ? feasible with fossil fuels nor with biomass-derived fuels respectively through imports) Stationary sector: Supply of back-up power via fuel cells (hospitals, telecom, data processing, manufacturing processes, refrigeration, etc.) Remote /re-electrification for electrical islands (compensation for infrastructure deficits) 17 Load levelling of fluctuating electricity productionwww.lbst.de Hidrógeno: “Fuente al Consumidor” Electricidad Renovable Electrolisis y Liquificación ludwig bölkow systemtechnik Reformador de Gas Natural Reformador de Biomasa Transporte Aplicaciones Móviles Almacenamiento der Hidogeno Aplicaciones Estacionarias Energía Doméstica Hidrógeno Químico 18 Red eléctrica Pila de Combusible www.lbst.de para Co-Generación Producción, compresión, almacenamiento y distribución del hidrógeno Mahler ludwig bölkow systemtechnik Linde onsite Air Liquide centralised Natural Gas Reformer Hydro-Pac Air Liquide Biomass Gasification DM2 Hydrogen Storage Linde Norsk Hydro PDC Hydrogenics BP 19 centralised Electrolyser onsite Hydrogen Compression Hydrogen www.lbst.de Dispenser Sistema de Isla en Utsira (Noruega) ludwig bölkow systemtechnik Energía eólica Pila de Combustible y Motor de Combustión Interna 20 Electrolisis y Almacenamiento www.lbst.de Suministro del hidrógeno como combustible renovable ludwig bölkow systemtechnik LH2 Hydrogen Delivery Certified Green Electricity Container/ Storage at Refueling Station Electrolyzer H2T H2T H2T Container Transportation Container Filling 21 Hydro Power Ocean Power Geothermal Power Source: LBST Wind Power Solar Power Biomass www.lbst.de Recursos de energías primarias para la producción del hidrógeno como combustible vehicular ludwig bölkow systemtechnik Solar Geothermal Wind Hydro Maritime Electricity Hydrogen Water Conventional [Coal, oil, natural gas, nuclear] Electrolysis Compressor Liquid hydrogen Import Storage (CGH2 p> 30 MPa) Natural gas with CCS Coal Single storage or cascade storage at different pressure levels Waste Steam Biomass 22 [Geological Hydrogen] Reformer www.lbst.de Fuentes del hidrógeno disponibles a corto plazo A proof for hydrogen‘s feedstock flexibility ... ludwig bölkow systemtechnik Chemical Hydrogen Pipeline Systems H2 Chemical By-Product Hydrogen 1 to 3 years 2 to 5 years 23 Refinery By-Product Hydrogen CGH2 Refuelling Station Natural Gas Reforming to Hydrogen Biomass Gasification to Hydrogen Stranded NG as LNG or Methanol Delivered Centralized or Onsite Reforming to Hydrogen Water Electrolysis www.lbst.de Estaciones de suministro de H2 en Alemania en 2005 hasta 2007 ludwig bölkow systemtechnik AGIP: FrankfurtHöchst [17NOV2006] Total: Berlin-Spandau [18NOV2005] Linde: Unterschleißheim (cerca de Munich) [09OCT2006] 24 Total: Munich [26APR2007] www.lbst.de 25 as ol in Di e ( es re el f er (re en fe ce) re CM nc e CM G ) G NG bi og a FA s M E BT L G TL C E t DM T L ha E M no N et ha E th l w G n o a n he l f ol a t ar m st ra CG M ed w H2 et h w o a o CG fa r no d l H2 m e N G d CG NG w o H2 (o od EU C n s e l G H i t e) ec 2 Ba c t ri t te c i o al ry CG ty m EV H2 i x EU w e l L H i nd ec 2 wi t ri nd ci ty m ix G [MJ/km] Consumo de energía en perspectiva “Pozo a Rueda” 4,50 4,00 3,50 3,00 Internal combustion engine (ICE) Fuel cell (FC) 2,00 1,50 ludwig bölkow systemtechnik Renewable Nuclear Fossil 2,50 Reference Diesel Propulsion 1,00 0,50 0,00 www.lbst.de 26 as ol in Di e ( es re el f er (re en fe ce) re CM nc e CM G ) G NG bi og a FA s M E BT L G TL C E t DM T L ha E M no N et ha E th l w G n o a n he l f ol a t ar m st ra CG M ed w H2 et h w o a o CG fa r no d l H2 m e N G d CG NG w o H2 (o od EU C n s e l G H i t e) ec 2 Ba c t ri t te c i o al ry CG ty m EV H2 i x EU w e l L H i nd ec 2 wi t ri nd ci ty m ix G [g CO 2 equivalent/km] Emisiones de gases inverandero en perspectiva “Pozo a Rueda” 350 Internal combustion engine (ICE) 250 200 Fuel cell (FC) 300 150 100 ludwig bölkow systemtechnik N2O CH4 CO2 Reference Diesel Propulsion 50 0 www.lbst.de Potencial de producción de combustibles vehiculares de origen renovable EU25 después de 2020 15000 Rail PJ/a Inland navigation 12500 ludwig bölkow systemtechnik The potentials of different alternatives are shown and can not be added. Civil aviation 10000 7500 Road transport Plantation (short rotation forestry) Plantation (grasses: 10-25 t TS/ha/a) 5000 Residual wood, residual straw 5,75% share of biofuels Via biogas 2500 0 max Demand min (Transport) Biogas 2002 1) (Methane) 1) 2) 27 min max Hydrogen (CGH2) min max Wasserstoff (LH2) min max BTL min max Plant oil/ FAME 2) min max Ethanol from wheat 2) min max Ethanol via SSCF Source: IEA-Statistics 2001-2002 Gross (without the energy efforts for the supply of the fuels e.g. the use of external energy for the ethanol plant) Data compilation and graphics: LBST www.lbst.de Potenciales técnicos para hidrógeno obtenido por electricidad renovable EU 25 después 20020 PV2) [PJ/yr] 20000 Solarthermal power stations 18000 16000 Ocean power Inland navigation Rail ludwig bölkow systemtechnik Geothermal Civil aviation 2) Wind onshore Road transport Wind offshore 14000 2) 2) 12000 10000 8000 6000 4000 2000 0 28 1) 2) Fuel consumption (Transport 2002) 1) Source: IEA-Statistics 2001-2002 still exploitable within the EU min CGH2 max min Hydropower Data compilation and graphics: LBST 2) max LH2 www.lbst.de Rendimiento por ha y año para diferentes combustibles de transporte ludwig bölkow systemtechnik Yield [GJfinal fuel/(ha yr)] 800 700 600 Assumptions H2: • Area occupied with PV: 33% • Solar irradiation: 900 kWh/(m2 yr) • Efficiency PV modules: 15% 500 • Performance Ratio: 75% • Efficiency CGH2 supply: 60% 400 • Efficiency LH2 supply: 54% 300 • 2.4 wind turbines/km2 • 2000 kW/wind turbine • Equivalent full load period WT: 1800 h/yr 200 *) *) Bandwidth 100 er dp wi n 2 LH w in d po ow w er PV 2 PV CG H2 LH CG H2 Bi o di es el (R Et M ha E) Et no h an ls ho ol w rt he ro at ta tio n fo re st ry Bi om et ha CG ne H2 sh or tr BT ot LH L at io 2 n sh fo or re tr st ot ry at io n fo re st ry 0 *) more than 99% of the land area can still be used for other purposes e.g. agriculture 29 Source: LBST www.lbst.de Cantidad de coches (hibridizados) que se puede proveer por ha Annual mileage passenger vehicle: 12,000 km ludwig bölkow systemtechnik [Passenger vehicles/ha] 80 70 Diesel engine 60 Otto engine 50 Fuel cell 40 30 Reference vehicle: VW Golf *) 20 10 *) Bandwidth er dp wi n 2 LH w in d po ow w er PV 2 PV CG H2 LH CG H2 Bi o di es el (R Et M ha E) E th no an ls ol ho w rt he ro at ta tio n fo re st ry Bi om et ha CG ne H2 sh or tr BT ot LH L at io 2 n sh fo or re tr st ot ry at io n fo re st ry 0 *) more than 99% of the land area can still be used for other purposes e.g. agriculture 30 Source: LBST www.lbst.de Costos combustible por contenido energético y emisiónes “Pozo a Tanque” 300 ludwig bölkow systemtechnik w tax Gasoline/Diesel 100 US$/barrel (w tax) w/o tax CGH2 from NG (onsite SMR): 380 - 440 g/kWh ~ 0,80 EUR/lGE) CO2 equivalent [g/kWh] 100 US$/barrel (w/o tax) EtOH (Wheat) EtOH (sugar beet) 200 100 Rapeseed oil CGH2 (Residual wood) RME EtOH (Residual wood) MeOH (Residual wood) 0 CMG (Biogas) 0 0,5 FT-Diesel (short rotation forestry) CGH2 (Wind) LH2 (Wind) LH2 (Residual wood) 1 FT-Diesel (Residual wood) 1,5 2 LH2 (SOT) 2,5 Source: LBST Fuel costs [EUR/lgasoline equivalent] 31 www.lbst.de Costos combustible por contenido energético y emisiónes “Pozo a Rueda” 200 100 US$/barrel (w/o tax) Gasoline/Diesel CO2 equivalent [g/km] 150 ludwig bölkow systemtechnik w/o tax EtOH (Wheat) w tax EtOH (sugar beet) • CGH2, LH2: FC • Methanol: FPFC • Diesel, RME, Rapeseed oil, FT diesel: Diesel ICE • Gasoline, ethanol, CMG: Otto ICE CGH2 (NG) 100 Rapeseed oil RME CMG (Biogas) 50 FT-Diesel (Residual wood) CGH2 (Residual wood) 0 0 MeOH (Residual wood) 0,02 EtOH (Residual wood) FT-Diesel (short rotation forestry) LH2 (Wind) CGH2 (Wind) 0,04 0,06 LH2 (Residual wood) ¾ Reference vehicle VW Golf ¾ Non-hybrid 32 LH2 (SOT) 0,08 Source: LBST Fuel costs [EUR/vehicle-km] www.lbst.de InWent Workshop Buenos Aires 27+28 September 2007 ludwig bölkow systemtechnik International Development and Demonstration Activities in Europe/Germany, USA, Japan and China 33 www.lbst.de Vehículos de hidrógeno producido en Alemania (2002-2006) Audi, BMW, DaimlerChrysler, MAN, GM/Opel, VW DC Hygenious F600 DC FC Citaro ludwig bölkow systemtechnik Audi A2 FC Hybrid GM/Opel HydroGen3 DC FC Sprinter MAN H2 ICE Bus GM Equinox “HydroGen4” 34 HyMotion VW Touran FC www.lbst.de BMW LH2 ICE Desarrollos Europeos en autobuses de pila de combustible (2000-2007) PM FC Hybrid bus 2000 ludwig bölkow systemtechnik DaimlerChrysler Citaro Ballard PEMFC bus – 2002 BVG articulated bus (LH2) – original planning 2006 35 ARGEMUC-MAN Ballard PEM fuel cell hybrid bus - 2004 Hybrid FC Europolis - 2007 www.lbst.de Desarrollos N. Americanos en autobuses de pila de combustible (2005-2006) Winnipeg FC bus - 2007 36 Santa Clara VTA Gillig Ballard PEMFC bus - 2005 ludwig bölkow systemtechnik AC Transit / UTC FC hybrid bus - 2006 Hydrogenics NRW FC bus - 2005 www.lbst.de Desarrollos en autobuses de pila de combustible en Japón/ China/ Korea (2001-2006) Toyota / Hino Fuel Cell Bus - 2001 ludwig bölkow systemtechnik Tsinghua University & DICP FCB 100 kW - 2004 Shanghai Shenli, Shanghai Jiao Tong University, Suzhou Chuangyuan Group, Suzhou Golden Dragon Bus Co Ltd. Hyundai FC bus - FIFA World Cup 2006 [certified for German roads by TÜV SÜD] 37 www.lbst.de FC City Bus - 2006 Desarrollos en caretillas elevadoras de pilas de combustible (2003–2006) ludwig bölkow systemtechnik Proton Motor FC/ Still ' FC forklifter' 2003 38 DOD forklift truck - 2006 Toronto ' FC forklifter' - 2004 Toyota forklift truck - 2005 www.lbst.de Aplicaciones de pilas de combustible pequeñas con tecnología alemana NovArs 2000 +2002 Aprilia 2003 Wolf 2003 Kärcher 2002 ludwig bölkow systemtechnik Masterflex 2005 no 39 Hunter 2003 Sortimo Proton Motor FC 2003 www.lbst.de Aplicaciones de pilas de combustible pequeñas con tecnología alemana ludwig bölkow systemtechnik Cargobike (Masterflex, Gelsenkirchen, NRW, Alemania) Bicicletas a PdC de alquilar (Herten, NRW, Alemania) 40 www.lbst.de Aplicaciones de pilas de combustible pequeñas con tecnología alemana Kap Arkona, MV, Alemania ludwig bölkow systemtechnik Müritz, MV, Alemania 41 Barcos sin emisiones de ruido ni de polución www.lbst.de Aplicaciones de pilas en ferrocarriles ..... East Japan Railroad FC Commuter Train (2006/2007 Adtranz FC Commuter Train Layout Study (2001) 42 ludwig bölkow systemtechnik European FC Train Project initiated in Denmark (2006) www.lbst.de Desarrollos en sistemas estacionarias de pilas de combustible - PEM ludwig bölkow systemtechnik CHP, Beta-Unit, 2006 Demonstration project CHP in the Netherlands GenCore PremiomT ElectraGen 43 www.lbst.de Desarrollos en sistemas estacionarias de pilas de combustible – SOFC ludwig bölkow systemtechnik Production plan in NRW New 2.5 MW for Baden-Württemberg under development (2012) APU (Webasto) CHP (Webasto-Vaillant) 44 www.lbst.de Desarrollos en sistemas estacionarias de PdC cogeneradoras ludwig bölkow systemtechnik 45 Hexis (SOFC) Vaillant (PEM) www.lbst.de Generadores pequeños de PdC (aprox. 1 kWel) ludwig bölkow systemtechnik Ballard (Hidrógeno, componente de sistemas) 46 Smart Fuel Cells (Metanol, producto final de venta) www.lbst.de Aplicaciones de pilas de combustible pequeñas y protatiles Marca Angstrom, Canada Antorcha con PdC y hidruros metálicos 47 ludwig bölkow systemtechnik Cargador con conexión USP www.lbst.de Páginas web de LBST Páginas web operadas por LBST Information on Hydrogen and Fuel Cells: www.HyWeb.de Information on the availability of fossil energy sources: www.Energiekrise.de All Hydrogen Refueling Stations Worldwide: www.h2stations.org All Hydrogen and FC Vehicles Worldwide: www.h2mobility.org 48 www.HyLights.org ludwig bölkow systemtechnik www.hfpeurope.org www.HyApproval.org www.HyWays.de www.HyNet.info www.EIHP.org a r G o p s a i c u s r n e t a ! n ció www.lbst.de InWent Workshop Buenos Aires 27+28 September 2007 ludwig bölkow systemtechnik Back up 49 www.lbst.de Estudios “Pozo a Rueda” [2001/ 2002/ 2004] ludwig bölkow systemtechnik http://www.transportation.anl.gov http://www.lbst.de/gm-wtw http://ies.jrc.cec.eu.int GM WtW North America GM WtW Europe CONCAWE/EUCAR/JRC Source: GM/Opel – OCT2005 50 www.lbst.de